Risk assessment of TBT in the Japanese short-neck clam (Ruditapes philippinarum) of Tokyo Bay using a chemical fate model     

Fumio Horiguchi  Kisaburo Nakata  Naganori Ito  Ken Okawa 《Estuarine, Coastal and Shelf Science》2006,70(4):589

A risk assessment of Tributyltin (TBT) in Tokyo Bay was conducted using the Margin of Exposure (MOE) method at the species level using the Japanese short-neck clam, Ruditapes philippinarum. The assessment endpoint was defined to protect R. philippinarum in Tokyo Bay from TBT (growth effects). A No Observed Effect Concentration (NOEC) for this species with respect to growth reduction induced by TBT was estimated from experimental results published in the scientific literature. Sources of TBT in this study were assumed to be commercial vessels in harbors and navigation routes. Concentrations of TBT in Tokyo Bay were estimated using a three-dimensional hydrodynamic model, an ecosystem model and a chemical fate model. MOEs for this species were estimated for the years 1990, 2000, and 2007. Estimated MOEs for R. philippinarum for 1990, 2000, and 2007 were approximately 1–3, 10, and 100, respectively, indicating a declining temporal trend in the probability of adverse growth effects.A simplified software package called RAMTB was developed by incorporating the chemical fate model and the databases of seasonal flow fields and distributions of organic substances (phytoplankton and detritus) in Tokyo Bay, simulated by the hydrodynamic and ecological model, respectively.  相似文献   

An overview of the Oyashio ecosystem   总被引：3，自引：0，他引：3  

Yasunori Sakurai   《Deep Sea Research Part II: Topical Studies in Oceanography》2007,54(23-26):2526

The Oyashio shelf region and the seasonally ice-covered areas north of Hokkaido are highly productive, supporting a wide range of species including marine mammals, seabirds and commercially important species in the western subarctic Pacific. The fishes include gadids, such as walleye pollock and Pacific cod, and subarctic migratory pelagic fishes such as chum salmon and pink salmon. It is also an important summer feeding ground for subtropical migrants such as the Japanese sardine, Japanese anchovy, Pacific saury, mackerels, Japanese common squid, whales and seabirds. In recent decades, some components of the Oyashio ecosystem (i.e., phytoplankton, mesozooplankton, gadid fish, and subtropical migrants) have shown changes in species abundance or distribution that are correlated with environmental changes such as the 1976/1977 and 1988/1989 regime shifts. The First Oyashio Intrusion moved northward from the mid-1960s until the late 1970s, when it moved southward until the 1980s, after which it returned to the north again after the mid-1990s. The sea-surface temperature in spring decreased after the late 1970s, increased after the late 1980s, and remained high during the 1990s. The extent of ice cover in the Sea of Okhostk also decreased during the latest warming in the 1980–1990s but has increased again since the late 1990s. This and other variabilities affect the Oyashio ecosystem and the surrounding region.  相似文献   

珠江口水域化学耗氧量、溶解氧、无机磷与有机磷的三维水质数学模拟   总被引：12，自引：0，他引：12       下载免费PDF全文

林卫强  李适宇 《海洋学报》2003,25(3):129-137

珠江沿岸城市排污量大,对污染源治理能力十分有限,大量污染物通过河流或直接排放到珠江口,河口区半封闭的地形及潮水顶托使得污染物不易输送出外海,致使珠江口水质恶化,原有海洋生态环境遭到破坏,反过来制约了经济的发展.  相似文献   

海洋褐藻胶生产废水的絮凝-氧化处理研究   总被引：2，自引：0，他引：2  

单宝田  赵中华  胡立阁  侯海军  马根之  王修林 《海洋科学》2002,26(11):31-34

使用新型高效的絮凝剂Xp，对海洋褐藻胶生产废水进行絮凝，催化氧化处理试验，确定了絮凝剂Xp的最佳使用条件，催化氧化时间和氧化剂用量，结果表明，经本工艺处理后，废水中主要污染物CODcr的去除率达到83．9％，处理后的废水基本达到国家《污水综合排放标准》（GB8978－1996）限定的二级标准。  相似文献   

山东省大中型水库水化学性状研究──几种主要水化因子的变化及其在评价水库鱼产力中的作用     

刘新  李德尚  李静 《中国海洋大学学报(自然科学版)》1994,(4)

本文通过对山东省３８座代表性大、中型水库总氮（ＴＮ）、总磷（ＴＰ）、化学耗氧量、硬度及电导率（λ）五种主要水化因子连续两年（１９８９～１９９０）的调查与研究，探讨了水化因子与水库鱼产力的关系。用反映鲢、鳙生长状况的综合生长指数（ＧＩ）作为水库鱼产力的指标。它与水化因子相关分析表明，总磷是山东省３８座水库鱼产力的主要影响因子。提出ＧＩ与总磷、总氮及电导率等水化因子的逐步回归方程关系非常显著。证明利用水化因子作为水库鱼产力的评价指标是可行的。并指出：同一水库的相同水化因子存在年间差异，其主要原因在于降雨量和水库进水量的不同，鉴于此．同一水库鱼产力也存在年间差异。  相似文献   

论氢化物的形成及其在分析测试领域的应用          下载免费PDF全文

郑大中  王惠萍  郑若锋 《江苏地质》2008,32(1):5-11

论述了氢化物形成的普遍性、氢化物的物理化学性质、元素周期系各类元素的氢化物类型。认为一些金属离子、非金属离子在酸性介质中与硼氢化钾（钠）作用及金属锌等强还原剂作用生成氢化物。综述了氢化物的形成在分析测试领域的应用：试样分解、分离富集、容量分析、光度分析、原子光谱分析、质谱分析。  相似文献   

长江流域河水和悬浮物的锂同位素地球化学研究   总被引：9，自引：1，他引：8  

汪齐连  刘丛强  赵志琦  丁虎 《地球科学进展》2008,23(9):952-958

深入理解流域侵蚀过程中的锂同位素分馏对于运用锂同位素来示踪化学循环和气候变化是十分必要的。研究集中在长江干流和主要支流的水体和悬浮物的锂及锂同位素组成。长江流域水体的锂及锂同位素组成（δ⁷Li）分别为150~4 570 nmol/L和+7.6‰~+28.1‰,两者沿上游至下游的变化趋势相反。悬浮物锂同位素组成（δ⁷Li）变化比较稳定,分别为41~92 μg/g和-4.7‰~+0.7‰,而且总是低于相应水体的锂同位素组成。悬浮物和流体之间的锂同位素分馏系数在0.977和0.992之间,与悬浮物的量及组成存在明显相关性,反映了粘土矿物的吸附和化学风化的程度。锂含量与锂同位素组成之间良好的负相关性表明流域水体的锂来自2个端元混合：其一可能是蒸发盐岩,并伴有深部热泉水;其二可能是硅酸岩。  相似文献   

化学地层学研究中的若干注意事项     

刘疆  白志强 《物探与化探》2008,32(4):345-349

化学地层学因其交叉学科特点和研究对象的复杂性使得研究过程中任何一个环节的不足都将造成测试出现偏差,成果的可信度也将出现问题。高昂的成本也要求研究者把有限的资源集中到正确的目标上。近20年研究历程却恰恰将此类性质的问题陆续暴露了出来。如采样阶段获取原生性状考虑不充分或依据不足、测试阶段缺乏校验、数据分析阶段挖潜和综合利用有待完善以及化学岩、碎屑岩和生物岩各自的基础性和针对性研究有待提高等。有些问题带有相当程度的普遍性,有些甚至是严重的核心技术问题。笔者结合最新相关研究成果对上述问题进行了逐一分析和系统修正。  相似文献   

Effect of Bacillus mucilaginosus on weathering of phosphorite and a preliminary analysis of bacterial proteins   总被引：3，自引：0，他引：3  

Shu Chen  Bin Lian  Congqiang Liu 《中国地球化学学报》2008,27(2):209-216

The authors investigated the effect of Bacillus mucilaginosus on weathering of phosphorite. Analysis of different proteins was of significance in exploring the molecular biological mechanism in the bacterial weathering process. The concrete methods are described as follows： Mineral powder was put into liquid culture medium and B. mucilaginosus was incubated in the medium. The control （group） had no mineral powder in the medium. The treatments and controls were cultured simultaneously under the same condition. In a few days, the supernatant was filtrated, the main cations （Ca^2＋, Mg^2＋, Na^＋, Mn^2＋, Al^3＋, Fe^3＋, K^＋） were measured by ICP-OES, and the contents of water soluble phosphorus （Pws） and silicon （Siws） were determined by colorimetry. The residual solid was weighed on the filter paper, followed by digestion with concentrated HNO3. The concentrations of the main cations and Pws, Siws in the digest liquid were measured by using the method mentioned above. After the supernatant was centrifuged, the precipitation was used to analyze the protein differences between the treatment groups and the control groups by 2-dimentional gel electrophoresis （2-DE）. The experimental results showed that apatite and quartz were partially weathered, but kaolinite was dissolved completely. The population of bacteria increased when mineral powder was added in the liquid medium. Software analysis and comparison of the 2-DE pictures of bacterial proteins revealed 1134 visible protein spots in the treatment group, and 729 visible protein spots in the control group. To compare the bacterial protein expression contents of the treatment group with those of the control group, there were 496 different protein spots, including 214 protein spots which indicated that the protein contents increased, 75 protein spots were indicative of a decrease, and 207 proteins were newly synthesized. It is proposed that the increased bacterial contents may be related to some protein expression and activation after the  相似文献   

斜坡非饱和带低渗透岩石结构体风化前锋扩展过程   总被引：2，自引：0，他引：2  

徐则民 《地学前缘》2008,15(4):258-268

非饱和带低渗透岩石结构体风化前锋扩展是斜坡灾害孕育过程中的关键环节之一。到目前为止,化学风化领域的研究成果主要集中在高水-岩比的饱和环境下单矿物及矿物成分单一的碳酸盐岩的风化动力学方面,非饱和环境下的岩石风化研究还主要限于风化产物的特性描述方面。斜坡非饱和带低渗透岩石结构体风化前锋扩展是一种高度复杂的THMC过程。由于在溶解对象、溶解液及溶解过程的水动力-水化学环境等方面存在的显著差异,既有的地质材料风化动力学成果为探索这一复杂过程提供了理论储备,但还不能阐明其核心机理。斜坡非饱和带低渗透岩石结构体风化前锋的扩展过程研究不仅可以加深人们对斜坡灾害孕育的理解,为灾害预报-预警及其控制提供理论依据,同时可以促进岩石-岩体力学及浅表生水文地球化学等相关学科的交叉与发展。  相似文献